Abstract
We assess current approaches to measurement uncertainty (MU) with respect to the complete ensemble of sources affecting the measurement process, in particular the extent to which sampling errors as set out in the Theory of Sampling (TOS) are appropriately considered in the GUM and EURACHEM/CITAC guides. All pre-analysis sampling steps play an important, often dominant role in the total uncertainty budget, thereby critically affecting the validity of MU estimates, but most of these contributions are not included in the current MU framework. The TOS constitutes the only complete theoretical platform for dealing appropriately with the entire pathway from field sample to test portion. We here propose a way to reconcile the often strongly felt differences between MU and TOS. There is no need to debate terminology, as both TOS and MU can be left with their current usages.
| Original language | English |
|---|---|
| Pages (from-to) | 93-106 |
| Number of pages | 14 |
| Journal | TrAC - Trends in Analytical Chemistry |
| Volume | 57 |
| DOIs | |
| Publication status | Published - May 2014 |
Keywords
- Correct sampling error
- EURACHEM/CITAC
- GUM
- Inconstant sampling bias
- Incorrect sampling error
- Measurement uncertainty
- Sampling bias
- Sampling error
- Theory of sampling
- Total sampling error
Programme Area
- Programme Area 3: Energy Resources
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