Emerging contaminants in polluted waters: Harnessing Biochar's potential for effective treatment

Biochar is a carbon-rich, sponge-like material with intricate functionalities, making it suitable for various environmental remediation applications, including water treatment, soil amendment and, additives in construction materials, anaerobic digesters, and electrodes, among others. Its easy adaptability and low cost make it particularly attractive. This review highlights a range of biochar and surface-modified biochar exhibiting high uptake and degradation efficiencies for a broad spectrum of contaminants, including humic acid, disinfection by-products (DBPs), radioactive materials, dyes, heavy metals, antibiotics, microplastics, pathogens, Per- and polyfluoroalkyl substances (PFAS), and cytotoxins. The study provides a detailed discussion on different classes of pollutants and their removal mechanisms using biochar, covering processes like physical and chemical adsorption, electrostatic interactions, π-π interactions, hydrogen bonding, as well as surface complexation, chelation, among others. This review article stands out for its comprehensive exploration of biochar's effectiveness in removing a wide range of emerging contaminants, as well as recent advancements in the removal of conventional pollutants like heavy metals and antibiotics.