Co-evolution of pyrite d66Zn and sphalerite-pyrite-galena modal proportions in the ca. 1,828 Ma Mississippi Valley type Zn-Pb Black Angel deposit, Greenland: insights into the chemical potential of sedimentary carbonates for Zn mineralization.

Nicolas Saintilan, Corey Archer, Kristoffer Szilas, Diogo Rosa

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingspeer-review

Abstract

The Black Angel deposit formed 1828 ± 17 million years ago (pyrite Re-Os model age) in a
foreland basin setting to the advancing Rinkian and Nagssugtoqidian orogens. Mineralizing processes were active at the time of building of the Rinkian foreland foldand-thrust system. A source of Os, and by corollary other metals, in the Archean Rae Craton is identified in
sphalerite-pyrite ± galena samples. A co-evolution of d66Znpyrite with sulfide modal proportions is evident. The narrow and uniform d66Znpyrite composition of sphaleritepyrite ± galena samples (+0.30 to +0.33‰), which overlaps with d66Zn of the upper continental crust (+0.35 ± 0.05 ‰), may be compatible with Zn saturation caused by dissolution/assimilation of carbonate which would result in near-quantitative sphalerite precipitation. Conversely, d66Znpyrite in the massive pyrite body and in pyrite-galena ± sphalerite samples (+0.14 to +0.21‰) associated with more pelitic carbonate is compatible with disequilibrium conditions and rapid precipitation without sufficient carbonate dissolution/replacement to reach near-neutral pH for sphalerite precipitation. We further assume that the difference of metal
endowment between Zn-Pb carbonatehosted and Pb-Zn sandstone-hosted MVT deposits could be related to dissolution of Zn-bearing, clean, sedimentary carbonate rocks that control sphalerite saturation and precipitation.
Original languageEnglish
Title of host publicationProceedings of the 17th Biennial Meeting of the Society for Geology Appled to Mineral Deposits
Place of PublicationZurich
PublisherSociety for Geology Applied to Mineral Deposits (SGA)
Pages335-338
Number of pages4
Volume2
Publication statusPublished - 30 Aug 2023
Event17th SGA Biennial Meeting : Mineral Resources in a Changing World - Zurich, Switzerland
Duration: 28 Aug 20231 Sept 2023
https://sga2023.ch/

Conference

Conference17th SGA Biennial Meeting
Country/TerritorySwitzerland
CityZurich
Period28/08/231/09/23
Internet address

Programme Area

  • Programme Area 4: Mineral Resources

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